MTHPA Hluav taws xob rwb thaiv tsev Technical Data

MTHPA Technical Data Package for Hluav taws xob rwb thaiv tsev

Methyl Tetrahydrophthalic Anhydride rau siab -voltage casting, potting, encapsulation thiab composite rwb thaiv tsev Cheebtsam

Hom ntaub ntawv	Cov ntaub ntawv txheej txheem rau epoxy-anhydride hluav taws xob rwb thaiv tsev tshuab
Daim phiaj siv	Transformers, ntsuas transformers, bushings, insulators, switchgear, busbars thiab fais fab modules
Khoom siv System	Bisphenol{0}}A epoxy resin / MTHPA / accelerator / functional fillers
Hnub tim	2026-05-11

Cov lus ceeb toom tseem ceeb: Cov formulations yog engineering references thiab tsis hloov ntau lawm validation, kev soj ntsuam xyuas, txheej txheem tsim nyog, los yog zaum kawg hom kev xeem los ntawm tus neeg muas zaub.

1. Cov ntsiab lus tseem ceeb

MTHPA (Methyl Tetrahydrophthalic Anhydride) yog cov kua cyclic anhydride curing tus neeg saib xyuas dav siv hauv epoxy systems rau hluav taws xob rwb thaiv tsev. Piv nrog rau ntau yam amine-kho tshuab, epoxy-anhydride systems feem ntau muab qis exotherm, lub lauj kaub ntev dua, qis shrinkage, muaj zog dielectric kev ua tau zoo, thermal stability thiab zoo mechanical zog. Cov yam ntxwv no ua rau MTHPA haum rau lub tshuab nqus tsev, tsis siv neeg siab gelation (APG), potting, impregnation thiab cov khoom siv hluav taws xob sib xyaw rau nruab nrab - thiab siab - cov khoom siv hluav taws xob.

Cov pob no tsom rau kev siv hluav taws xob engineering es tsis yog cov khoom siv hluav taws xob siv dav dav: cov khoom siv hluav taws xob, siab -voltage rwb thaiv tsev, kev xa tawm thiab kev xa tawm, txuas ntxiv dua - hluav taws xob daim phiaj sib txuas, hluav taws xob hluav taws xob thiab kev tsheb nqaj hlau- cov khoom siv hluav taws xob.

2. Daim ntawv thov hluav taws xob Scope thiab cov khoom lag luam

Kev thov qeb	Yam khoom	Lub luag haujlwm ntawm MTHPA-raws li Epoxy	Cov khoom tseem ceeb Validation
High -voltage cast rwb thaiv tsev	Tam sim no transformers, voltage transformers, bushings, txhawb insulators, nplhaib -main-unit rwb thaiv tsev qhov chaw	Curing, rwb thaiv tsev, thermal kuj thiab txhua yam kev txhawb nqa	Dielectric lub zog, ib feem tawm, ntim resistivity, Tg, flexural zog, thermal cycling
Qhuav- hom transformers thiab coil casting	Qhuav-hom transformer coils, kawg rwb thaiv tsev, coil encapsulation	Flowability, txo shrinkage thiab txo qis hauv kev ntxhov siab	Gel lub sij hawm, exotherm, tawg tsis kam, thermal laus, tiv taus voltage
Switchgear thiab busbar systems	Embedded ncej, busbar rwb thaiv tsev, switchgear barriers	Rwb thaiv tsev, kev txhawb nqa, arc tsis kam thiab ya raws	CTI, arc kuj, creepage, nplaim tsis kam, dej nqus
Fais fab-electronics potting	IGBT/SiC modules, EV- charger power modules, inverter, fais fab mov transformers	Kev tiv thaiv potting, thermal rwb thaiv tsev, kev vibration thiab noo noo kuj	Thermal conductivity, dielectric poob, thermal cycling, adhesion
Motors thiab rail transit	Traction motor rwb thaiv tsev, ruaj rwb thaiv tsev qhov chaw, sensor encapsulation	Txhim khu kev rwb thaiv tsev thiab tiv thaiv - kev tiv thaiv kev co	Chav kawm kub, mechanical shock, damp heat, ntsev -spray resistance

3. Cov khoom zoo rau hluav taws xob rwb thaiv tsev

Tsawg viscosity: haum rau siab - puv tshuab, nqus tsev degassing, complex pwm filling thiab loj- ntim casting.
Lub neej ntev lauj kaub: pab tau rau APG, casting thiab impregnation txheej txheem tswj.
Tsawg shrinkage thiab tswj exotherm: pab txo cov kev ntxhov siab sab hauv, tawg thiab void tsim nyob rau hauv tuab - ntu ntu.
Cov khoom siv hluav taws xob zoo heev: tsim nyog rau kev ntim siab, tsis muaj dielectric poob thiab siab dielectric zog yuav tsum tau.
Zoo thermal thiab mechanical kev ua tau zoo: txhawb qhov seem stability, mechanical zog thiab thermal aging kuj.
Zoo compatibility nrog inorganic fillers: silica, alumina, txhuas hydroxide, magnesium oxide thiab lwm yam fillers yuav siv tau los txhim kho qhov ntev stability, thermal conductivity los yog nplaim taws.

4. Formulation Design Logic

Ib qho nyuaj epoxy-anhydride formulation yuav tsum tsis txhob cia siab rau qhov kev siv tshuaj "80-95 phr" nkaus xwb. Lub formulation yuav tsum tau xam los ntawm epoxy sib npaug qhov hnyav (EEW), anhydride sib npaug qhov hnyav (AHEW), lub hom phiaj sib npaug piv thiab qib accelerator.

Parameter	Txhais	Engineering Lub ntsiab lus
EEW	Epoxy sib npaug Nyhav, g / eq	Loj ntawm resin muaj ib qho sib npaug ntawm epoxy pawg. Hom kua DGEBA epoxy resin yog nyob ib ncig ntawm 185-192 g / eq.
AW	Anhydride sib npaug hnyav, g / eq	Loj ntawm anhydride muaj ib qho sib npaug reactive. Rau MTHPA, siv tus xa khoom COA / TDS lossis xam los ntawm tus nqi kua qaub.
r	Anhydride / epoxy sib npaug piv	Rau hluav taws xob casting, 0.85-1.05 yog ib qho kev loj hlob ntau yam thiab yuav tsum tau optimized los ntawm Tg, dielectric, mechanical thiab exotherm validation.
phr	Yam ib puas resin	Cov khoom ntxiv rau 100 qhov chaw epoxy resin.

Kev suav: MTHPA ntau npaum li cas (phr)=100 × AHEW / EEW × r. Piv txwv li: yog EEW=190 g/eq, MTHPA AHEW kwv yees ntawm 166 g/eq thiab r=0.95, MTHPA ≈ 100 × 166 / 190 × 0.95=83 phr. Yog tias r=1.00, qhov ntau npaum li cas yog li 87 phr. Cov koob tshuaj tiag tiag yuav tsum raug kho siv qhov tseeb COA qhov tseem ceeb.

Accelerators xws li DMP-30, BDMA, imidazoles thiab quaternary ammonium/phosphonium ntsev yuav siv tau. Rau qhov loj hluav taws xob castings, latency, gel lub sij hawm, exotherm ncov, lub neej lub lauj kaub thiab ib feem-tso tawm tsis xws luag yog ib qho tseem ceeb tshaj qhov tsuas yog ua kom tiav kev kho sai.

5. Pom zoo Engineering Formulation Systems

Code	Daim ntawv thov	Epoxy cob	MTHPA	Accelerator	Filler	Cov lus pom
F-01	General HV casting / ntsuas transformers	DGEBA EEW 185-192: 100 phr	82-90 hnub; kho los ntawm EEW/AHEW	DMP-30 0.2-0.6 phr los yog BDMA 0.3-0.8 phr	Silica 250-350 phr	Sib npaug ntws, lub zog thiab kev ua haujlwm dielectric; haum raws li lub hauv paus.
F-02	APG embedded ncej / bushings	DGEBA 100 phr; reactive diluent Tsawg dua los yog sib npaug li 5 phr yog xav tau	82-88 : kuv	Latent imidazole los yog quaternary ntsev 0.05-0.30 phr	Silica 300-450 phr	Yuav tsum tau ceev gelation thiab tsis xws luag; phim pwm kub thiab siab.
F-03	Qhuav- hom transformer coil casting	DGEBA 100 phr + toughener 5-12 phr	80-88 : kuv	BDMA 0.2-0.6 phr los yog DMP-30 0.1-0.4 phr	Silica / alumina 250-400 phr	Tsom ntsoov rau exotherm, kev ntxhov siab sab hauv, tawg thiab nqus impregnation.
F-04	Thermally conductive insulating potting / hwj chim electronics	DGEBA 100 phr; reactive diluent 3-8 phr yog xav tau	80-90 dr hab	Imidazole / BDMA 0.1-0.5 phr	Alumina 300-600 phr los yog Al2O3+BN sib tov	Sib npaug thermal conductivity, rwb thaiv tsev, viscosity thiab tiv thaiv -tawm.
F-05	Nplaim taws- rwb thaiv tsev tsis zoo / switchgear	DGEBA 100 phr	82-90 : kuv	DMP-30 0.2-0.5 phr	Silica 200-300 phr + ATH 100-250 phr	Kev ntsuas nplaim taws yuav tsum raug kuaj; saib xyuas dej nqus thiab dielectric poob.
F-06	Thermal-cycling-cov rwb thaiv tsev tiv thaiv	DGEBA 100 phr + CTBN/core-plhaub toughener 3-10 phr	80-88 : kuv	BDMA 0.2-0.6 phr	Silica 250-350 phr	Rau thermal cycling lossis vibration; toughness yuav txo Tg.

Daim ntawv ceeb toom: cov no yog cov ntsiab lus pib engineering, tsis yog cov qauv tsim khoom kawg. MTHPA ntau npaum li cas, accelerator hom thiab muab tub lim yuav tsum tau ua kom zoo raws li lub hom phiaj Tg, ib feem tawm, dielectric poob, gel lub sij hawm, exotherm ncov, viscosity profile, cia stability thiab cov pwm geometry.

6. Cov txheej txheem pom zoo qhov rai

Txheej txheem txheej txheem	Tswv yim Parameters	Tswj Cov Ntsiab Lus
Raw-cov ntaub ntawv preheating	Epoxy 50-70 degree; MTHPA 40-60 degree; fillers qhuav ntawm 80-120 degree	Txo cov viscosity thiab noo noo los tiv thaiv npuas, ntxuav hniav dawb thiab ib nrab - paug tsis xws luag.
Sib tov	Nqus los yog qis- shear mixing; zam huab cua nkag	Ntxiv cov fillers hauv batch; tswj kub nce thiab viscosity.
Degassing	Kwv yees li . -0.095 MPa lub tshuab nqus tsev rau 20-60 min nyob ntawm viscosity	Tsis txhob haus dej ntau dhau; tuab -section castings yuav tsum tau degassing txaus.
Casting/APG	Pwm 80-140 degree; siab thiab pwm kub yuav tsum tau txuas rau hauv APG	Flow pem hauv ntej, gel point thiab venting tsim txiav txim siab theem.
Tshaj tawm - kho	80℃× 2h + 120℃× 4h + 140-150℃× 4-8h; optimize los ntawm Tg	Kev kub ceev heev yuav ua rau muaj kev ntxhov siab thiab tawg. Siv cov kauj ruam cua sov rau qhov loj.
Txias	Lub qhov cub qeeb qis qis dua 60℃ua ntej demolding	Txo thermal shock thiab tawg.

7. Cov khoom xeem tseem ceeb thiab cov phiaj xwm pom zoo

Qeb	Cov kev ntsuam xyuas pom zoo	Hom Lub Hom Phiaj / Ua kom pom tseeb
Cov khoom hluav taws xob	Dielectric zog, ntim resistivity, dielectric tas li, dielectric poob, arc kuj, CTI, ib nrab paug	HV rwb thaiv tsev qhov yuav tsum tau PD thiab tiv taus - qhov ntsuas hluav taws xob; hluav taws xob hluav taws xob yuav tsum tsis muaj dielectric poob ntawm qhov kub thiab txias.
Thermal khoom	Tg los ntawm DSC / DMA, tshav kub deflection, thermal conductivity, thermal aging	Tg yuav tsum ntev tshaj -lub sij hawm ua hauj lwm kub nrog ib tug kev nyab xeeb margin.
Mechanical zog	Flexural zog, tensile zog, cuam tshuam lub zog, tawg toughness, hardness	Siab - cov tshuab ua kom muaj zog tuaj yeem muaj zog tab sis qis dua toughness.
Txheej txheem khoom	Viscosity-kub nkhaus, gel lub sij hawm, exotherm ncov, lub neej lauj kaub, tiv thaiv-tawm	Txiav txim siab kev tsim khoom ruaj khov thiab qib tsis raug.
Ib puag ncig kev ntseeg tau	Thermal cycling, damp cua sov, ntsev tsuag, dej nqus, tshuaj tiv thaiv	Qhov tseem ceeb rau sab nraum zoov, tsheb ciav hlau, rov ua dua - zog thiab EV daim ntawv thov.

8. Hom kev ua tsis tiav thiab kev tiv thaiv

Hom kev ua tsis tiav	Tej Yam Ua Tau	Kev tiv thaiv
Kev tawg	High exotherm, ceev txias, tsis zoo muab tub lim, siab shrinkage	Txo accelerator; nce muab tub lim; siv cov kauj ruam kho; ntxiv toughener.
Siab ib nrab tso tawm	Npuas, microcracks, noo noo, interface tsis xws luag	Cov ntaub ntawv qhuav; nqus degas; optimize qhov rooj / qhov cua tsim; siv silane-kho cov fillers.
Low Tg	Tsawg anhydride piv, kho tsis tiav, tsis haum accelerator	xam los ntawm EEW/AHEW; nce ncej- kho; kho accelerator.
viscosity ntau dhau	High muab tub lim loading, tsis zoo particle packing, tsis tshua muaj kub, resin aging	Optimize muab tub lim; nce preheat kub; siv tsawg-viscosity resin/reactive diluent.
High dielectric poob	Moisture, ionic impurities, filler contamination, kho tsis tiav	Tswj noo noo / acid tus nqi / ions; siv siab -purity fillers; txhim kho ncej- kho.

9. Kev Tswj Xyuas Kev Tswj Xyuas Zoo thiab cov khoom xa tuaj

Raw Khoom	Qhov taw qhia tseem ceeb	Yog vim li cas rau kev tswj
MTHPA	Cov tsos mob, xim, acid tus nqi / AHEW, viscosity, dej, dawb acid, purity / isomer stability	Muaj feem xyuam rau ntau npaum li cas, kho tus nqi, dielectric kev ua tau zoo, xim thiab cia ruaj khov.
Epoxy cob	EEW, viscosity, hydrolyzable chlorine, inorganic chlorine, xim, dej	Muaj feem cuam tshuam rau kev ua haujlwm hluav taws xob, sib npaug sib npaug thiab kev cia siab ntev ntev -.
Accelerator	Assay, kev ua ub no, dej, cia ruaj khov	Muaj feem xyuam rau lub sijhawm gel, exotherm thiab lub neej lub lauj kaub.
Filler	Particle-loj faib, whiteness, noo noo, ionic impurities, kho deg	Muaj feem xyuam rau viscosity, kev daws teeb meem, dielectric zog, ib feem tawm thiab mechanics.

10. Ntim, Cia thiab Kev Nyab Xeeb

MTHPA yuav tsum tau muab khaws cia rau hauv cov thawv ntim khoom kom tsis txhob muaj dej nkag. Cov dej noo tuaj yeem cuam tshuam rau lub nplhaib anhydride qhib, kho cov tshuaj tiv thaiv thiab kev ua haujlwm dielectric.

Khaws rau hauv qhov chaw txias, qhuav thiab qhov cua kom deb ntawm cov hauv paus muaj zog, oxidizers thiab dej.

Hnav looj tsom iav dub, tshuaj- hnab looj tes tiv thaiv thiab tiv thaiv khaub ncaws. Tsis txhob kov daim tawv nqaij thiab nqus pa.

Hluav taws xob- qib cov neeg siv khoom yuav tsum xav tau batch traceability, COA, TDS, SDS, hloov kev ceeb toom (PCN/4M) thiab cov qauv khaws cia.

11. Pom zoo rau cov neeg siv khoom validation Workflow

Theem	Lub hom phiaj	Cov zis
Lab kev tshuaj ntsuam	Xaiv qhov sib npaug piv, accelerator thiab muab tub lim	Viscosity, gel lub sij hawm, Tg, thawj dielectric thiab mechanical cov ntaub ntawv.
Pilot txheej txheem	validate lub tshuab nqus tsev casting / APG / potting txheej txheem qhov rais	Degassing, casting defects, exotherm, kho profile thiab seem tsom xam.
Khoom validation	Siv tau nyob rau hauv pwm tiag tiag thiab cov qauv hluav taws xob	Kev tso tawm ib nrab, tiv taus qhov hluav taws xob, thermal cycling, damp cua sov, kev laus thiab qhov ruaj khov.
Kev taw qhia txog kev tsim khoom	Tsim batch stability thiab QC cov qauv	SOP, QC tuaj, cov txheej txheem tsis ua haujlwm thiab tsis ua haujlwm- ntsuas lub voj.

12. Cov ntaub ntawv

1. Broadview Technologies, Methyltetrahydrophthalic Anhydride daim ntawv qhia: MTHPA yog piav raws li epoxy resin curing tus neeg sawv cev rau casting, potting, impregnation thiab lamination nrog tsawg noo noo uptake thiab ruaj khov qis -viscosity sib tov.

2. Dixie Chemical / TRI ISO, Formulation Guide - Anhydride Curatives rau Epoxy Systems: anhydride curatives yog siv nyob rau hauv siab -voltage hluav taws xob daim ntawv thov thiab encapsulation ntawm hluav taws xob Cheebtsam thiab circuits.

3. Li et al., Molecules, 2023, "Curing Regime-Modulating Insulation Performance of Anhydride-Cured Epoxy Resin: A Review": tham txog anhydride-kho bisphenol-A epoxy insulation systems thiab DMP-30 a

4. Han li al., Polymer Degradation thiab Stability, 2022: MTHPA tau sau tseg tias yog ib qho tshuaj anhydride curing tus neeg sawv cev uas tsis muaj viscosity, lub neej ntev lauj kaub thiab zoo hluav taws xob rwb thaiv tsev rau cov khoom siv hluav taws xob loj xws li transformers thiab hluav taws xob insulators.

5. Cov ntaub ntawv patent ntawm epoxy resin compositions rau hluav taws xob rwb thaiv tsev hais txog cov kua epoxy resin, cyclic anhydride hardener, hluav taws xob insulating fillers thiab amine catalysts rau siab - cov khoom siv hluav taws xob kub.

MTHPA Hluav taws xob rwb thaiv tsev cov ntaub ntawv